Electron Transfer Reactions at Elevated Pressures.
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چکیده
منابع مشابه
Biological electron-transfer reactions.
A wide range of biological processes makes extensive use of electron-transfer reactions. Rigorous characterization of a biological electron-transfer reaction requires a combination of kinetic, thermodynamic, structural and theoretical methods. The rate of electron transfer from an electron donor to an electron acceptor through a protein is dependent on the difference in reduction potential of t...
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The mechanism for electron transfer is discussed in terms of an atomic motion on a potential-energy surface in many-dimensional atomic configuration space. In the absencc of electronic coupling between the reactants, a surface for the reactants intersects one for the products. Electronic coupling causes the usual removal of this degcncracy and permits the products to be formed adiabatically or ...
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While diabatic approaches are ubiquitous for the understanding of electron-transfer reactions and have been mooted as being of general relevance, alternate applications have not been able to unify the same wide range of observed spectroscopic and kinetic properties. The cause of this is identified as the fundamentally different orbital configurations involved: charge-transfer phenomena involve ...
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ژورنال
عنوان ژورنال: THE REVIEW OF HIGH PRESSURE SCIENCE AND TECHNOLOGY
سال: 1998
ISSN: 0917-639X,1348-1940
DOI: 10.4131/jshpreview.8.193